An international team of researchers, led by faculty at the University of Michigan, have found that a layered form of graphene can expel heat efficiently, which is an important feature for its potential applications in building small and powerful electronics.
“As you make devices smaller and smaller, you increase the amount of heat generated in a limited space, so you need to find ways to extract the heat,” said Momchil Mihnev, a doctoral student in electrical engineering and computer science at the University of Michigan and first author on the paper in Nature Communications.
Graphene, a one-atom-thick sheet of carbon, has been hailed as the future of electronics because of its outstanding electrical conductivity. But a number of challenges stand between its promise and its adoption in commercial devices.
One difficulty is simply producing the stuff. Arguably, the most reliable method is baking silicon carbide, a compound of silicon and carbon atoms, so that the silicon evaporates out, leaving behind a layered graphene structure. This type of graphene is most promising for electronic devices.
But unlike heat in a 3D chunk of silicon, heat building up in the electrons of graphene was not expected to travel well between layers, since graphene layers tend not to interact with each other very strongly. Meanwhile, the chunk of silicon can conduct heat in any direction.
Now, researchers led by Theodore Norris, the Gérard A. Mourou Collegiate Professor of Electrical Engineering and Computer Science, have shown the electrons can transmit heat efficiently between layers, enabling it to rapidly dissipate out of the 3D graphene. Mihnev explained that although the electrons in different layers can’t mechanically run into one another, they can interact through their electrical charges.
The negative charges repel one another, giving the electrons an effective size that extends between the layers. When electrons collide in this way, the hotter of the two transfers energy to the colder. The heat is channeled into the graphene layers closest to the silicon carbide base because these layers had borrowed extra electrons from the silicon carbide. From there, the heat moves into the silicon carbide.
“The reliability and performance of future graphene-based devices will depend critically on the availability of efficient mechanisms for the dissipation of excess generated heat,” Mihnev said.
Norris’s team studied graphene samples produced by the group of Walter de Heer, a Regent Professor and professor of physics at the Georgia Institute of Technology in Atlanta. They shot a short and intense burst of laser light into the sample, causing the electrons to heat up to about 5,000°F. Then, they used a weak pulse of radiation that falls between far infrared and microwave on the electromagnetic spectrum to check the temperature of the electrons in the graphene.
John Tolsma, co-first-author with Mihnev and a doctoral student in physics, and Allan MacDonald, the Sid W. Richardson Foundation Regents Chair Professor of Physics, both at The University of Texas at Austin, worked out a detailed new theory to explain the effect.
“We believe that this cooling mechanism is not limited to multilayer graphene samples but is likely to be important in many other new, layered nanomaterials under active development by the scientific community,” said Norris.
The paper on this work is called “Electronic cooling via interlayer Coulomb coupling in multilayer epitaxial graphene.” The study was supported in part by the National Science Foundation, the Welch foundation and the Department of Energy.
Electronic cooling via interlayer Coulomb coupling in multilayer epitaxial graphene, Momchil T. Mihnev, John R. Tolsma, Charles J. Divin, Dong Sun, Reza Asgari, Marco Polini, Claire Berger, Walt A. de Heer, Allan H. MacDonald, and Theodore B. Norris
Ted Norris - Gérard A. Mourou Collegiate Professor of Electrical Engineering and Computer Science
Momchil Mihnev- Research fellow in Prof. Norris' group
Charles J. Divin - Doctoral student in Prof. Norris' group
Allan MacDonald - Sid W. Richardson Foundation Regents Chair Professor of Physics, University of Texas
John Tolsma - Doctoral student in Prof. MacDonald's group
Dong Sun - Int. Center for Quantum Materials, School of Physics, Peking University, Beijing, China
Reza Asgari - School of Physics, Institute for Research in Fundamental Sciences, Tehran, Iran
Marco Polini - Graphene Labs, Istituto Italiano di Tecnologia, Genova, Italy
Claire Berger - School of Physics, Georgia Institute of Technology, Atlanta, Georgia
Walt A. de Heer - School of Physics, Georgia Institute of Technology, Atlanta, Georgia